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Best NLO Crystals in OptoCity

Physical and Optical Properties of NLO Crystals

NLO Crystal
BBO
LBO
BIBO
KTP
LN
KDP
KD*P
KTA
RTP
Formula
BaB2O4
LiB3O5
BiB3O6
KTiOPO4
LiNbO3
KH2PO4
KD2PO4
KTiAsO4
RTiOPO4
Crystal Structure
Trigonal R3c
Orthorhombic mm2
Monoclinic
Orthorhombic mm2
Trigonal R3c
Orthorhombic mm2
Orthorhombic mm2
Cell Parameters (Angstrom)
a=12.532
8.4473
7.116
6.404
0.515
13.12
12.96
b=12.532
7.3788
4.993
10.616
0.515
6.56
10.56
c=12.717
5.1395
6.508
12.814
13.863
10.798
6.49
Melting Point
1095
834
726
936
1255
1130
1000
homogeneity
1.0E-6
1.0E-6
5E-5
Mohs hardness
4.5
6
5.5
5
5
5
Density(g/cm3)
3.85
2.47
5.033
3.01
4.64
3.45
3.6
Absorption
<0.1%
<0.1%
<0.1%
<0.1%
0.07/cm
0.006/cm
<0.1%/cm
0.05%
Hygroscopic
low
none
none
N/A
N/A
N/A
none
none
Electrical Conductivity
>1.0E11 ohm-cm
c: 3.5E-8 s/cm
0.7-3.4E-6 s/cm
1E-8 s/cm
Relative Dielectric Constant

6.7(11) 8.1(33)

13
85(11) 29.5(33)
42(33)
13.0(33)
Thermal Expansion Coefficients
4E-6
10.8E-5
4.8E-5
2.0E-6
1.01E-5
-8.8E-5
4.4E-5
1.37E-5
36E-6
3.4E-5
-2.69E-5
2.2E-6
4.17E-6
Thermal Conductivity
a:1.2 c:1.6 W/m-K
0.13 W/m-K
38 W/m-K
a:1.8 b:1.9 c:2.1W/m-K
NLO Coefficients (pm/V)
d11=2.55 d22<0.13 d31=0.13
d31=1.05 d32=-0.98 d33=0.05
d11=2.53 d12=2.3 d13=-1.3 d14=2.3 d25=2.4 d26=2.8 d35=-0.9 d36=2.4
d15=1.91 d24=3.64 d31=2.54 d32=5.35 d33=16.9
d15=5.95 d22=3.07 d31=5.95 d33=34.4
d36=0.44
d36=0.40
d15=2.3 d24=3.2 d31=2.8 d32=4.2 d33=16.2
d15=2.0 d24=3.6 d31=2.0 d32=3.6 d33=8.3
Electro-Optic Coefficients (pm/V)
r11=2.7 r22<0.1r11 r31<0.1r11
r13=9.5 r23=15.7 r33=36.3 r51=7.3 r42=9.3
r22=6.8 r31=10 r33=32
r41=8.8 r63=10.3
r41=8.8 r63=25
r13=11.5 r23=15.4 r33=37.5
r13=10.6 r23=12.5 r33=35
Damage Threshold*
5GW/cm2
9.5GW/cm2
2.5GW/cm2
200 MW/cm2
5GW/cm2
3GW/cm2
15J/cm2
600 MW/cm2
Transparency Range (nm)
189-3500
160-2600
286-2500
350-4500
420-5200
200-1500
200-1600
350-5300
350-4500
Refractive Indices @1064nm
no=1.6551
nx=1.5656
nx=1.7573
nx=1.7377
no=2.322
no=1.4938
no=1.4948
nx=1.782
ny=1.5905
ny=1.7840
ny=1.7453
ny=1.790
ne=1.5425
nz=1.6055
nz=1.9172
nz=1.8297
ne=2.156
ne=1.4599
ne=1.4554
nz=1.868

Therm-Optic Coefficients (/deg. C)

-9.3E-6
-9.3E-6
1.1E-5
-13.6E-6
1.3E-5
-16.6E-6
-6.3+2.1*WL
1.6E-5
Sellmeier Equations
n=A+B/(WL**2 -C) -D*WL**2 --- WL=Wavelength in um
n=A+B*WL**2 /(WL**2-C**2) -D*WL**2
A1
2.7359
2.454140
3.0740
3.0065
4.9048
2.259276
1.9575544
1.90713
2.5559
B1
0.01878
0.011249
0.0323
0.03901
0.11768
0.01008956
0.0290139
1.23522
0.93307
C1
0.01822
0.011350
0.0316
0.04251
0.04750
0.012942625
0.0281399
0.19692
0.20994
D1
0.01354
0.014591
0.01337
0.01327
0.027169
0.03259454
0.02824391
0.01025
0.01452
A2
2.3753
2.539070
3.1685
3.0333
4.5820
2.132668
1.5005779
2.15912
2.38494
B2
0.01224
0.012711
0.0373
0.04154
0.099169
0.008637494
0.6276034
1.00099
0.73603
C2
0.01667
0.012523
0.0346
0.04547
0.04443
0.01228104
0.0131558
0.21844
0.23891
D2
0.01516
0.018540
0.01750
0.01408
0.021950
0.0080902
0.01054063
0.01096
0.01583
A3
2.586179
3.6545
3.3134
2.14768
2.27723
B3
0.013099
0.0511
0.05694
1.29559
1.11030
C3
0.011893
0.0371
0.05658
0.22719
0.23454
D3
0.017968
0.02260
0.01682
0.01436
0.01995
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